The new C-C bond formation in the reaction of o-amidophenolate indium(III) complex with alkyl iodides.
Identifieur interne : 000326 ( Main/Exploration ); précédent : 000325; suivant : 000327The new C-C bond formation in the reaction of o-amidophenolate indium(III) complex with alkyl iodides.
Auteurs : RBID : pubmed:23760142Abstract
The reaction of bis(4,6-di-tert-butyl-N-(2,6-di-iso-propylphenyl)-o-amidophenolato)indium(III) anion with alkyl iodides is reported. This process includes oxidative addition of two RI (R = Me, Et) molecules to the non-transition metal complex and results in an alkyl transfer to ring carbon atoms with the formation of two new C-C bonds. The interaction proceeds at mild conditions and gives new indium(III) derivatives containing iminocyclohexa-1,4-dienolate type ligands.
DOI: 10.1039/c3dt50934f
PubMed: 23760142
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<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">The new C-C bond formation in the reaction of o-amidophenolate indium(III) complex with alkyl iodides.</title><author><name sortKey="Piskunov, Alexandr V" uniqKey="Piskunov A">Alexandr V Piskunov</name><affiliation wicri:level="1"><nlm:affiliation>G.A. Razuvaev Institute of Organometallic Chemistry of Russian Academy of Sciences, 49 Tropinina Street, 603950 Nizhny Novgorod, Russia. pial@iomc.ras.ru</nlm:affiliation><country xml:lang="fr">Russie</country><wicri:regionArea>G.A. Razuvaev Institute of Organometallic Chemistry of Russian Academy of Sciences, 49 Tropinina Street, 603950 Nizhny Novgorod</wicri:regionArea></affiliation></author><author><name sortKey="Meshcheryakova, Irina N" uniqKey="Meshcheryakova I">Irina N Meshcheryakova</name></author><author><name sortKey="Fukin, Georgy K" uniqKey="Fukin G">Georgy K Fukin</name></author><author><name sortKey="Shavyrin, Andrei S" uniqKey="Shavyrin A">Andrei S Shavyrin</name></author><author><name sortKey="Cherkasov, Vladimir K" uniqKey="Cherkasov V">Vladimir K Cherkasov</name></author><author><name sortKey="Abakumov, Gleb A" uniqKey="Abakumov G">Gleb A Abakumov</name></author></titleStmt><publicationStmt><date when="2013">2013</date><idno type="doi">10.1039/c3dt50934f</idno><idno type="RBID">pubmed:23760142</idno><idno type="pmid">23760142</idno><idno type="wicri:Area/Main/Corpus">000583</idno><idno type="wicri:Area/Main/Curation">000583</idno><idno type="wicri:Area/Main/Exploration">000326</idno></publicationStmt></fileDesc><profileDesc><textClass></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">The reaction of bis(4,6-di-tert-butyl-N-(2,6-di-iso-propylphenyl)-o-amidophenolato)indium(III) anion with alkyl iodides is reported. This process includes oxidative addition of two RI (R = Me, Et) molecules to the non-transition metal complex and results in an alkyl transfer to ring carbon atoms with the formation of two new C-C bonds. The interaction proceeds at mild conditions and gives new indium(III) derivatives containing iminocyclohexa-1,4-dienolate type ligands.</div></front></TEI><pubmed><MedlineCitation Owner="NLM" Status="PubMed-not-MEDLINE"><PMID Version="1">23760142</PMID><DateCreated><Year>2013</Year><Month>07</Month><Day>03</Day></DateCreated><DateCompleted><Year>2014</Year><Month>01</Month><Day>22</Day></DateCompleted><Article PubModel="Print"><Journal><ISSN IssnType="Electronic">1477-9234</ISSN><JournalIssue CitedMedium="Internet"><Volume>42</Volume><Issue>29</Issue><PubDate><Year>2013</Year><Month>Aug</Month><Day>7</Day></PubDate></JournalIssue><Title>Dalton transactions (Cambridge, England : 2003)</Title><ISOAbbreviation>Dalton Trans</ISOAbbreviation></Journal><ArticleTitle>The new C-C bond formation in the reaction of o-amidophenolate indium(III) complex with alkyl iodides.</ArticleTitle><Pagination><MedlinePgn>10533-9</MedlinePgn></Pagination><ELocationID EIdType="doi" ValidYN="Y">10.1039/c3dt50934f</ELocationID><Abstract><AbstractText>The reaction of bis(4,6-di-tert-butyl-N-(2,6-di-iso-propylphenyl)-o-amidophenolato)indium(III) anion with alkyl iodides is reported. This process includes oxidative addition of two RI (R = Me, Et) molecules to the non-transition metal complex and results in an alkyl transfer to ring carbon atoms with the formation of two new C-C bonds. The interaction proceeds at mild conditions and gives new indium(III) derivatives containing iminocyclohexa-1,4-dienolate type ligands.</AbstractText></Abstract><AuthorList CompleteYN="Y"><Author ValidYN="Y"><LastName>Piskunov</LastName><ForeName>Alexandr V</ForeName><Initials>AV</Initials><Affiliation>G.A. Razuvaev Institute of Organometallic Chemistry of Russian Academy of Sciences, 49 Tropinina Street, 603950 Nizhny Novgorod, Russia. pial@iomc.ras.ru</Affiliation></Author><Author ValidYN="Y"><LastName>Meshcheryakova</LastName><ForeName>Irina N</ForeName><Initials>IN</Initials></Author><Author ValidYN="Y"><LastName>Fukin</LastName><ForeName>Georgy K</ForeName><Initials>GK</Initials></Author><Author ValidYN="Y"><LastName>Shavyrin</LastName><ForeName>Andrei S</ForeName><Initials>AS</Initials></Author><Author ValidYN="Y"><LastName>Cherkasov</LastName><ForeName>Vladimir K</ForeName><Initials>VK</Initials></Author><Author ValidYN="Y"><LastName>Abakumov</LastName><ForeName>Gleb A</ForeName><Initials>GA</Initials></Author></AuthorList><Language>eng</Language><PublicationTypeList><PublicationType>Journal Article</PublicationType></PublicationTypeList></Article><MedlineJournalInfo><Country>England</Country><MedlineTA>Dalton Trans</MedlineTA><NlmUniqueID>101176026</NlmUniqueID><ISSNLinking>1477-9226</ISSNLinking></MedlineJournalInfo></MedlineCitation><PubmedData><History><PubMedPubDate PubStatus="entrez"><Year>2013</Year><Month>6</Month><Day>14</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="pubmed"><Year>2013</Year><Month>6</Month><Day>14</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="medline"><Year>2013</Year><Month>6</Month><Day>14</Day><Hour>6</Hour><Minute>1</Minute></PubMedPubDate></History><PublicationStatus>ppublish</PublicationStatus><ArticleIdList><ArticleId IdType="doi">10.1039/c3dt50934f</ArticleId><ArticleId IdType="pubmed">23760142</ArticleId></ArticleIdList></PubmedData></pubmed></record>Pour manipuler ce document sous Unix (Dilib)
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